Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines.
نویسندگان
چکیده
Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.
منابع مشابه
The formation of a hydrated homochiral helix from an achiral zwitterionic salt, spontaneous chiral symmetry breaking and redox chromism of crystals.
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عنوان ژورنال:
- Chemical communications
دوره 51 20 شماره
صفحات -
تاریخ انتشار 2015